Volumetric Properties of Binary Mixtures of 2-Ethoxyethanol and 2-Butoxyethanol with 1,4-Dioxane

Authors

  • Mohammad Mafizur Rahman Department of Chemistry, University of Chittagong, Chittagong-4331, Bangladesh
  • Md. Ariful Islam Department of Chemistry, University of Chittagong, Chittagong-4331, Bangladesh
  • Faisal I Chowdhury Department of Chemistry, University of Chittagong, Chittagong-4331, Bangladesh
  • Muhammad A. R. Khan Department of Chemistry, University of Chittagong, Chittagong-4331, Bangladesh
  • Shamim Akhtar Department of Chemistry, University of Chittagong, Chittagong-4331, Bangladesh

DOI:

https://doi.org/10.33736/jaspe.4904.2023

Keywords:

Excess molar volumes; Partial molar volumes; Excess thermal expansivities; 2-Butoxyethanol; 2-Ethoxyethanol; 1, 4-Dioxane

Abstract

Densities, r, of 2-Ethoxyethanol (EGMEE) + 1,4-Dioxane (DXN) and  2-Butoxyethanol (EGMBE) + 1,4-Dioxane (DXN) systems have been measured in the whole range of composition at an interval of 5 K ranging from 303.15 to 323.15 K. Excess molar volumes, , partial molar volumes, , thermal expansivities,a, and excess thermal expansivities, aE, have been estimated from the experimental values of ρ. All of the derived properties have been fitted to appropriate polynomials. Values of   and aE were fitted to the Redlich-Kister polynomial equation and their variations with composition and temperature have been discussed in terms of molecular interaction in the mixtures. Values of  and aE were all positive and were attributed due to specific interactions.

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Published

2023-04-30

How to Cite

Mohammad Mafizur Rahman, Md. Ariful Islam, I Chowdhury, F., Muhammad A. R. Khan, & Shamim Akhtar. (2023). Volumetric Properties of Binary Mixtures of 2-Ethoxyethanol and 2-Butoxyethanol with 1,4-Dioxane. Journal of Applied Science &Amp; Process Engineering, 10(1), 1–20. https://doi.org/10.33736/jaspe.4904.2023

Issue

Vol. 10 No. 1 (2023): Journal of Applied Science & Process Engineering, Volume 10, Number 1, 2023

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