Preparation and Characterization of Activated Carbon from Pandanus candelabrum Stem

  • PAUL EGWUONWU DIM Federal University of Technology Minna
  • AUGUSTINE UGOCHUKWU ILOKA
  • JOSEPH ONYEBUCHI OKAFOR Department of Chemical Engineering, Federal University of Technology, Minna

Abstract

Pandanus candelabrum stem, a new precursor, was used to synthesise activate carbon. The effect of sodium hydroxide, NaOH, zinc (II) chloride, ZnCl2 and phosphoric acid, H3PO4, different agents on prepared adsorbents was investigated. The adsorbents were prepared with chemical agents and carbonized at 400 oC for 1 hour. Surface morphology, elemental composition and functional groups were analysed with scanning electron microscopy (SEM), energy dispersive X-ray (EDX), X-ray diffraction (XRD) and fourier transform infrared spectroscopy (FTIR), respectively. The image analysis showed the presence of both micropores and mesopores in the adsorbents. The H3PO4 activated carbon had the maximum surface area (2648 m2/g), pore volume (1.683 cm3/g) and highest adsorption for iodine and methylene blue were 541 and 105 mg/g. Pandanus candelabrum stem is an alternative material that can be used to synthesis high porous adsorbent because is abundant, easy to access, inexpensive and readily available.

 

Keywords: Activated, adsorption, iodine number, methylene blue, Pandanus candelabrum, reagents

Author Biography

PAUL EGWUONWU DIM, Federal University of Technology Minna

Dr Paul Egwuonwu DIM,

Assistant Professor

Department of Chemical Engineering

Federal University of Technology, Minna, Nigeria

References

Ademiluyi, F. T. & Nze, J. C. (2016). Multiple adsorption of heavy metal ions in aqueous solution using activated carbon from Nigerian Bamboo. International Journal of Research in Engineering and Technology, 5 (1): 164-169.

https://doi.org/10.15623/ijret.2016.0501033

Akpabio U.D. & Akpakpan, A.E. (2012). Pulp and paper from agricultural wastes: Plantain pseudostem wastes and screw pine leaves. International Journal of Modern Chemistry, 2 (3):100-107.

Baba, S., Hung, T. C., Mio, K.., Tomomi, I. & Eric, W. C. C. (2016). Artocarpus altilis and Pandanus tectorius: Two important fruits of oceania with medicinal values. Journal of Food and Agriculture, 28 (8): 531-539.

https://doi.org/10.9755/ejfa.2016-02-207

Budinova, T., Ekinci, E., Yardım, F., Grimm, A., Björnborn, E. & Minkova, V. (2006). Characterization and application of activated carbon produced by H3PO4 and water vapor activation. Fuel Process Technology, 87:899-905.

https://doi.org/10.1016/j.fuproc.2006.06.005

Cadavid, Y., Cadena, E.M., Velez, J.M. & Santa, J.F. (2016). Degradation of dyes using plantain fibers modified with nanoparticles. In R. Fangueiro and S. Rana (eds.), Natural Fibres: Advances in Science and Technology Towards Industrial Applications, RILEM Book series 12. pp.99-112.

https://doi.org/10.1007/978-94-017-7515-1_8

Cleiton, N. A. & Guerreiro, M. C. (2011). Estimation of surface area and pore volume of activated carbons by methylene blue and iodine numbers. Quím. Nova, 34 (3): 421-432.

https://doi.org/10.1590/S0100-40422011000300020

Danish, M., Hashim, R., Ibrahim, M.N.M. & Sulaimon, O. (2014) Optimization study for preparation of activated carbon from Acacia magnum wood using phosphoric acid. Wood Science and Technology, 48: 1069-1083.

https://doi.org/10.1007/s00226-014-0647-y

Deng, H., Li, G.X., Yang, H.B., Tang, J.P. & Tang, J.Y. (2010). Preparation of activated carbons from cotton stalk by microwave assisted KOH and K2CO3 activation. Chemical Engineering Journal, 163: 373-381.

https://doi.org/10.1016/j.cej.2010.08.019

Dim, P.E. (2013). Adsorption of methyl red and methyl orange using different tree bark powder, Academic Research International, 4:(1) 330-338.

Dim, P.E., Olu, S.C. & Okafor, J.O. (2020). Kinetic and thermodynamic study of adsorption of Cu (II) and Cr (VI) ion from industrial effluent onto kaolinite clay. Journal of Chemical Technology and Metallurgy, 55 (5) :1057-1067.

Fillaeli, A., Kristianingrum, S., Siswani, E. D. & Fatimah S. D. (2019). Synthesis activated carbon of screw-pine leaves by HNO3 and its properties. Journal of Physics: Conf. Series 1156 (2019) 01200. doi:10.1088/1742-6596/1156/1/012001 (Accessed: 20 September 2020).

https://doi.org/10.1088/1742-6596/1156/1/012001

Foo, K.Y. & Hameed, B.H. (2012). Potential of jackfruit peel as precursor for activated carbon prepared by microwave induced NaOH activation. Bioresource Technology, 112 :143-150.

https://doi.org/10.1016/j.biortech.2012.01.178

Giraldo, L., Rodriguez-Estupiñan, P. & Moreno-Piraján. J.C. (2018). A microcalorimetric study of methane adsorption on activated carbons obtained from mango peel at different conditions. Journal of Thermal Analysis and Calorimetry, 166: 552 - 556.

Gu, Z. & Wang, X. (2013). Carbon materials from high ash bio-char: a nanostructure similar to activated graphene. American Transactions on Engineering and Applied Sciences, 2:15 - 34.

Hassan, A.F., Abdel-Mohsen, A.M. & Fouda, M.M.G. (2014). Comparative study of calcium alginate, activated carbon, and their composite beads on methylene blue adsorption. Carbohydrate Polymers, 102 (1): 192-198.

https://doi.org/10.1016/j.carbpol.2013.10.104

Huang, Y. & Zhao, G. (2015). Preparation and characterization of activated carbon fibers from liquefied wood by KOH, Holzforschung, online, DOI: 10.1515/hf-2015-0051 (Accessed: 10 August 2020).

https://doi.org/10.1515/hf-2015-0051

Hussein, T.K. & Jasim, N.A. (2019). Removal of crystal violet and methylene blue from synthetic industrial wastewater using fennel seed as an adsorbent. Journal of Engineering Science and Technology, 14 (5): 2947-2963.

Kılıç, M, Apaydın-Varol, E. & Pütün, A.E. (2012). Preparation and surface characterization of activated carbons from Euphorbia rigida by chemical activation with ZnCl2, K2CO3, NaOH and H3PO4. Applied Surface Science, 261: 247-254.

https://doi.org/10.1016/j.apsusc.2012.07.155

Kumar, A. & Jena, H. M. (2017). Removal of methylene blue and phenol onto prepared activated carbon from fox nutshell by chemical activation in batch and fixed bed column. Journal of Cleaner Production, 137:1246-1259.

https://doi.org/10.1016/j.jclepro.2016.07.177

Liu, Y., Yao, X., Wang, Z., Li, H., Shen, X., Yao, Z. & Qian, F. (2019). Synthesis of activated carbon from citric acid residue by phosphoric acid activation for the removal of chemical oxygen demand from sugar-containing wastewater. Environmental Engineering Science, 36 (6): 656-666.

https://doi.org/10.1089/ees.2018.0506

Moreno-Virgen, M.D.R., Tovar-Gomez, R., Mendoza-Castillo, D.I. & Bonilla-Petriciolet, A. (2012). Applications of activated carbons obtained from lignocellulosic materials for the wastewater treatment, Instituto Tecnológico de Aguascalientes México, DOI: 10.5772/39367 (Accessed: 22 August 2020).

https://doi.org/10.5772/39367

Mario, A. T. & Hiromitsu, T. (2018). Chemistry of Pandanus alkaloids. International Journal of Chemistry and Biology, 82: 1-28.

Nafsun, A.I., Nasir, A.J., Jamal, M.N.M., Mohamad, S., Abdulrazik, A., Raja, D.D.S. & Herz, F. (2020). Influence of activation temperature and acid concentration on sludge-based activated carbon, IOP Conf. Ser.: Material Science and Engineering, 872 012064.

https://doi.org/10.1088/1757-899X/736/2/022052

Norouzi, S., Heidari, M., Alipour, V., Rahmanian, O., Fazlzadeh, M., Mohammadi-Moghadam, F., Nourmoradi, H., Goudarzi, B. & Dindarloo, K. (2018). Preparation, characterisation and Cr (VI) adsorption evaluation of NaOH activated carbon produced from Date Press Cake: An agro-industrial waste, Bioresource Technology, 258: 48-56.

https://doi.org/10.1016/j.biortech.2018.02.106

Nunes, C.A. & Guerreiro, M.C. (2011). Estimation of surface area and pore volume of activated carbons by methylene blue and iodine numbers. Quimica Nova, 34(3): 472-476.

https://doi.org/10.1590/S0100-40422011000300020

Rai, M.K., Shahi, G., Meena, V., Meena, R., Chakraborty, S., Singh, R.S. & Rai, B.N. (2016). Removal of hexavalent chromium Cr (VI) using activated carbon prepared from mango kernel activated with H3PO4. Resource-Efficient Technologies, 2: 63-70.

https://doi.org/10.1016/j.reffit.2016.11.011

Ramavandi, B. & Asgari, G. (2018). Comparative study of sun-dried and oven-dried Malva sylvestris biomass for high-rate Cu (II) removal from wastewater. Process Safety and Environmental Protection, 116: 61-73.

https://doi.org/10.1016/j.psep.2018.01.012

Sahira, J., Mandira, A., Prasad, P.B. & Ram, P.R. (2013). Effects of Activating Agents on the Activated Carbons Prepared from Lapsi Seed Stone. Research Journal of Chemical Sciences, 3(5): 19-24.

Shamsuddin, N.S., Yusoff, N.R.N. & Sulaiman, M.A. (2016). Synthesis and characterization of activated carbon produced from kenaf core fibre using H3PO4 activation. Procedia Chemistry, 19: 558 - 565.

https://doi.org/10.1016/j.proche.2016.03.053

Shrestha, R.M., Yadav, A.P., Pokharel, B.P. & Pradhananga, R. (2012). Preparation and characterization of activated carbon from Lapsi (Choerospondias axillaris) seed stone by chemical activation with phosphoric acid. Research Journal of Chemical Sciences, 2(10): 80-86.

Wang, T.H., Tan, S.X. & Liang, C.H. (2009). Preparation and characterization of activated carbon from wood via microwave-induced ZnCl2 activation. Carbon, 47: 1867-1885.

https://doi.org/10.1016/j.carbon.2009.03.035

Wang, Z., Wu, J., He, T. & Wu, J. (2014). Corn stalks char from fast pyrolysis as precursor material for preparation of activated carbon in fluidized bed reactor. Bioresource Technology, 167: 551-554.

https://doi.org/10.1016/j.biortech.2014.05.123

Wang, Z., Nie, E., Li, J. Zhao, Y., Luo, X. & Zheng, Z. (2011). Carbons prepared from Spartina alterniflora and its anaerobically digested residue by H3PO4 activation: characterization and adsorption of cadmium from aqueous solutions. Journal of Hazardous Materials, 188: 29-36.

https://doi.org/10.1016/j.jhazmat.2011.01.041

Yakout, T.M. & El-Deen, G.S. (2016). Characterization of activated carbon prepared by phosphoric acid activation of olive stones. Arabian Journal of Chemistry, 9: 1155-1162.

https://doi.org/10.1016/j.arabjc.2011.12.002

Yorgun, Y. & Yıldız, D. (2015). Preparation and characterization of activated carbons from Paulownia wood by chemical activation with H3PO4. Journal of the Taiwan Institute of Chemical Engineers, 24: 1-10.

https://doi.org/10.1016/j.jtice.2015.02.032

Zubrik, A., Matik, M., Hredzák, S., Lovás, M., Danková, Z., Kováčová, M. & Briančin, J. (2017). Preparation of chemically activated carbon from waste biomass by single-stage and two-stage pyrolysis, Journal of Cleaner Production, 137: 1236-1249.

https://doi.org/10.1016/j.jclepro.2016.12.061

Published
2020-12-30
How to Cite
DIM, P. E., ILOKA, A. U., & OKAFOR, J. O. (2020). Preparation and Characterization of Activated Carbon from Pandanus candelabrum Stem. Borneo Journal of Resource Science and Technology, 10(2), 105-115. https://doi.org/10.33736/bjrst.2700.2020